| Bill Nighy | ...Billy Mack |
| Gregor Fisher | ...Joe |
| Rory MacGregor | ...Engineer |
| Colin Firth | ...Jamie Bennett |
| Sienna Guillory | ...Jamie's Girlfriend |
| Liam Neeson | ...Daniel |
| Emma Thompson | ...Karen |
| Lulu Popplewell | ...Daisy, her daughter |
| Kris Marshall | ...Colin Frissell |
| Heike Makatsch | ...Mia |
| Martin Freeman | ...John |
| Joanna Page | ...Just Judy |
| Chiwetel Ejiofor | ...Peter |
| Andrew Lincoln | ...Mark |
| Keira Knightley | ...Juliet |
| Hugh Grant | ...The Prime Minister |
| Nina Sosanya | ...Annie |
| Frank Moorey | ...Terence, who's in charge |
| Jill Freud | ...Pat the housekeeper |
| Martine McCutcheon | ...Natalie |
| Tim Hatwell | ...Vicar |
| Laura Linney | ...Sarah |
| Lynden David Hall | ...The Wedding Singer |
| The Big Blue | ...Church musicians |
| Jont Whittington | ...Guitarist |
| Dan Fredenburgh | ...Jamie's bad brother |
| Julia Davis | ...Nancy the caterer |
| Abdul Salis | ...Tony |
| Alan Barnes | ...Movie director |
| Shaughan Seymour | ...Movie cameraman |
| Helen Murton | ...Funeral priest |
| Edward Hardwicke | ...Sam's grandfather |
| Caroline John | ...Sam's grandmother |
| Thomas Sangster | ...Sam |
| Gemma Aston | ...Family mourner |
| Matt Harvey | ...Family mourner |
| Adrian Preater | ...Family mourner |
| Joanna Thaw | ...Family mourner |
| Junior Simpson | ...Wedding DJ |
| Alan Rickman | ...Harry |
| Rodrigo Santoro | ...Karl |
| Brian Bovell | ...Radio Watford DJ |
| Sarah McDougall | ...Receptionist |
| Marcus Brigstocke | ...Mikey, DJ interviewer |
| Richard Hawley | ...Alex, Deputy Prime Minister |
| Wyllie Longmore | ...Jeremy |
| Gillian Barge | ...Cabinet Minister |
| Richard Wills-Cotton | ...Cabinet Minister |
| Kate Bowes Renna | ...Cabinet Minister |
| Kate Glover | ...Cabinet Minister |
| Nicola McRoy | ...Cabinet Minister |
| Ant McPartlin | ...Ant (as Anthony McPartlin) |
| Declan Donnelly | ...Dec |
| Elisabeth Margoni | ...Eleonore (as Elizabeth Margoni) |
| Lúcia Moniz | ...Aurelia |
| Billy Bob Thornton | ...The US President |
| Peter Marinker | ...US Expert |
| Keir Charles | ...Press Conference Reporter |
| Doraly Rosen | ...Press Conference Reporter |
| Meg Wynn Owen | ...PM's Secretary |
| Carol Carey | ...Natalie's replacement |
| Jo Whiley | ...Radio DJ |
| Sarah Atkinson | ...Billy's Video Vixen |
| Clare Bennett | ...Billy's Video Vixen |
| Sarah Holland | ...Billy's Video Vixen |
| Vicki Murdoch | ...Billy's Video Vixen |
| Meredith Ostrom | ...Billy's Video Vixen |
| Katherine Poulton | ...Billy's Video Vixen |
| Tuuli | ...Billy's Video Vixen |
| Michael Parkinson | ...Parky |
| Michael Fitzgerald | ...Michael, Sarah's brother |
| Rowan Atkinson | ...Rufus, jewellery salesman |
| William Wadham | ...Bernie, Karen's son |
| Catia Duarte | ...Language student |
| Igor Urdenko | ...Language student |
| Nat Udom | ...Language student |
| Ines Boughanmi | ...Language student |
| Yuk Sim Yau | ...Language student |
| John Sharian | ...Wisconsin taxi driver |
| Glenn Conroy | ...Barman |
| Ivana Milicevic | ...Stacey, American Dreamgirl |
| January Jones | ...Jeannie, American Angel |
| Elisha Cuthbert | ...Carol-Anne, American Goddess |
| Wes Butters | ...Radio 1 chart show DJ |
| Laura Rees | ...Record company executive |
| Emma Buckley | ...Jamie's sister |
| Sheila Allen | ...Jamie's mum |
| Terry Reece | ...PM's chauffeur, Terry |
| Colin Coull | ...PM's bodyguard, Gavin |
| Margery Mason | ...Harris Street old lady |
| Katharine Bailey | ...Harris Street little girl |
| Tiffany Boysell | ...Her friend |
| Georgia Flint | ...Her friend |
| Joanna Bacon | ...Natalie's mum |
| Bill Moody | ...Natalie's dad |
| Billy Campbell | ...Natalie's octopus brother, Keith |
| Paul Slack | ...John's brother |
| Adam Godley | ...Mr. Trench |
| Olivia Olson | ...Joanna Anderson |
| Ruby Turner | ...Mrs. Jean Anderson |
| Amanda Garwood | ...Backing-singer teacher |
| Arturo Venegas | ...Mr. Anderson |
| Claudia Schiffer | ...Carol |
| Patrick Delaney | ...Tommy, Carol's son |
| Helder Costa | ...Mr. Barros |
| Carla Vasconcelos | ...Sophia Barros |
| Stewart Howson | ...Airport gate man |
| Jamie Edgell | ...Airport guard |
| Dave Fisher | ...Airport guard |
| Paul Heasman | ...Airport guard |
| Tony Lucken | ...Airport guard |
| Raul Atalaia | ...Restaurant proprietor |
| Nancy Sorrell | ...Greta |
| Shannon Elizabeth | ...Harriet, the sexy one |
| Denise Richards | ...Carla, the real friendly one |
| Richard Curtis | ...Trombone player (uncredited) |
| Rebecca Frayn | ...Joanna, Daniel's dead wife (uncredited) |
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